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سنتز هیدروترمال و کارایی شبه‌خازنی نانو‌میله‌های β-NiMoO4

نوع مقاله : مقاله کامل پژوهشی

نویسندگان

1 استادیار، گروه مهندسی مواد، دانشکده مهندسی، دانشگاه ملایر، ملایر، همدان، ایران

2 کارشناسی ارشد، گروه مهندسی مواد، دانشکده مهندسی، دانشگاه ملایر، ملایر، همدان، ایران

چکیده

در این پژوهش، ماده فعال نانوساختار نیکل مولیبدات (NiMoO4)، به‌طور موفقیت‌آمیزی با استفاده از روش ساده هیدروترمال سنتز شد. مشخصه‌یابی ساختاری، با استفاده از پراش اشعه ایکس (XRD) و طیف‌سنجی تبدیل فوریه مادون‌قرمز (FTIR) و بررسی ریخت‌شناسی سطحی ماده حاصله به کمک میکروسکوپ الکترونی روبشی نشر میدانی انجام شد. نتایج نشان داد که ماده الکترودی به‌دست‌آمده، ساختار نانومتری، ریخت‌شناسی    میله­ای­شکل و ساختار بلوری فاز β دارد. بررسی‌های الکتروشیمیایی با استفاده از آزمون‌های ولتامتری چرخه­ای در نرخ روبش­های مختلف و شارژ-تخلیه جریان ثابت در چگالی جریان­های مختلف نشان داد که ماده فعال نیکل مولیبدات دارای ظرفیت ویژه بالای معادل 730 فاراد بر گرم در چگالی جریان 1 آمپر بر گرم و ابقای ظرفیت حدود 2/63 درصد با افزایش ده برابری چگالی جریان به 10 آمپر بر گرم است. نتایج به‌دست‌آمده حاکی از آن است که نانو­میله­های نیکل مولیبدات سنتز­شده می‌توانند کاندیدای مناسبی برای ماده الکترودی ابرخازن­هایی با کارایی بالا باشند.

کلیدواژه‌ها

عنوان مقاله [English]

Hydrothermal Synthesis and Pseudocapacitive Performance of β-NiMoO4 Nanorods

نویسندگان [English]

  • Mahdi Kazazi 1
  • Mina Ataie 2

1 Assistant Professor, Department of Material Engineering, Faculty of Engineering, Malayer University, Malayer, Hamedan, Iran

2 M. Sc., Department of Material Engineering, Faculty of Engineering, Malayer University, Malayer, Hamedan, Iran

چکیده [English]

Abstract     In this research, nanostructured nickel molybdate (NiMoO4) active material was successfully synthesized by a simple hydrothermal route. Structural characterizations were performed using X-Ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR), and surface morphology of the     as-prepared material was obtained by Field Emission Scanning Electron Microscopy (FESEM). The results showed that the as-prepared electrode material has a nanometric and rod-shaped structure and their crystal structure was β-phase. Electrochemical evaluations using cyclic voltammetry at various potential scanning rates and galvanostatic charge-discharge at various current densities show that nickel molybdate active material has the high specific capacitance of 730 F g-1 at a current density of 1 A g-1 and a capacity retention of about 63.2 % even with a 10-fold increase in current density to 10 A g-1. The obtained results imply that the as-synthesized NiMoO4 nanorods could be a promising candidate as electrode material for high performance supercapacitors.

کلیدواژه‌ها [English]

  • Supercapacitors
  • Nickel Molybdate
  • Hydrothermal Route
  • Nanorods
  • Electrochemical Performance
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مواد و فناوری‌های پیشرفته
دوره 10، شماره 3
آذر 1400
صفحه 57-65
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سابقه مقاله
  • تاریخ دریافت: 15 آذر 1399
  • تاریخ بازنگری: 13 دی 1399
  • تاریخ پذیرش: 10 آذر 1400
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