مواد و فناوری‌های پیشرفته

مواد و فناوری‌های پیشرفته

ساخت و مشخصه‌یابی آلیاژهای آنتروپی بالای چندجزئی زیست‌سازگار نوین تولیدشده به روش متالورژی پودر

نوع مقاله : مقاله کامل پژوهشی

نویسندگان
1 دانشجوی پسادکتری مهندسی مواد، گروه مهندسی و علم مواد، دانشکده فنی و مهندسی، دانشگاه بین‌المللی امام خمینی )ره(، قزوین، ایران
2 استاد، گروه مهندسی و علم مواد، دانشکده فنی و مهندسی، دانشگاه بین‌المللی امام خمینی (ره)، قزوین، ایران
10.30501/jamt.2026.563755.1350
چکیده
در این مطالعه، سه آلیاژ آنتروپی بالای زیست‌سازگار حاوی تیتانیم، زیرکونیم، نیوبیم و دو عنصر دیگر، با استفاده از فرایند آلیاژسازی مکانیکی و متالورژی پودر، سنتز شدند. هدف از این پژوهش، ارزیابی تأثیر جایگزینی عناصر Cr، Fe و V بر پایداری فاز، ریزساختار و خواص مکانیکی بود. نتایج XRD نشان‌دهندة ساختار اصلی BCC در هر سه آلیاژ و با کمترین فازهای فرعی HCP و بین‌فلزی در TiZrNbCrV بود. این آلیاژ با بالاترین کسر فاز BCC، کمترین تخلخل (۳/۱۱ درصد)، بیشترین سختی (۳۶۱ ویکرز)، بالاترین مقاومت فشاری (۱۰۵۵ مگاپاسکال) و مدول یانگ پایین (۲۴/۸ گیگاپاسکال)، بهترین عملکرد مکانیکی را داشت.
کلیدواژه‌ها
موضوعات

عنوان مقاله English

Synthesis and Characterization of Novel Biocompatible Multi-Component High-Entropy Alloys Produced by Powder Metallurgy

نویسندگان English

Masoud Yousefi 1
Ahmad Razaghian Arani 2
1 Postdoctoral Researcher in Materials Engineering, Department of Materials Science and Engineering, Faculty of Technical and Engineering, Imam Khomeini International University (IKIU), Qazvin, Iran.
2 Professor, Department of Materials Science and Engineering, Faculty of Technical and Engineering, Imam Khomeini International University (IKIU), Qazvin, Iran.
چکیده English

In this study, three biocompatible high-entropy alloys were synthesized via mechanical alloying and powder metallurgy. The objective was to evaluate the influence of substituting Cr, Fe, and V elements on phase stability, microstructure, and mechanical properties. XRD results revealed a primary BCC structure in all three alloys, with the lowest secondary HCP and intermetallic phases in TiZrNbCrV. This alloy exhibited the highest BCC phase fraction, lowest porosity (3.11%), highest hardness (361 Vickers), highest compressive strength (1055 MPa), and low Young's modulus (24.8 GPa), demonstrating the best mechanical performance.

کلیدواژه‌ها English

High Entropy Alloys
Powder Metallurgy
Biocompatible
1.        Castro, D., Jaeger, P., Baptista, A. C., & Oliveira, J. P. (2021). An overview of high-entropy alloys as biomaterials. Metals11(4), 648. https://doi.org/10.3390/met11040648
2.        Chang, Y. Y., & Huang, K. C. (2022). Improvement of tribological performance of TiAlNbN hard coatings by adding AlCrN. Materials15(21), 7750.  https://doi.org/10.3390/ma15217750
3.        Feng, R., Liaw, P. K., Gao, M. C., & Widom, M. (2017). First-principles prediction of high-entropy-alloy stability. npj Computational Materials3(1), 50. https://doi.org/10.1038/s41524-017-0049-4
4.        Hardin, R. A., & Beckermann, C. (2013). Effect of porosity on deformation, damage, and fracture of cast steel. Metallurgical and Materials Transactions A44(12), 5316-5332. https://doi.org/10.1007/s11661-013-1669-z
5.        Hori, T., Nagase, T., Todai, M., Matsugaki, A., & Nakano, T. (2019). Development of non-equiatomic Ti-Nb-Ta-Zr-Mo high-entropy alloys for metallic biomaterials. Scripta Materialia172, 83-87. https://doi.org/10.1016/j.scriptamat.2019.07.011
6.        Hu, S., Li, T., Su, Z., Meng, S., Jia, Z., & Liu, D. (2021). A novel TiZrNb medium entropy alloy (MEA) with appropriate elastic modulus for biocompatible materials. Materials Science and Engineering: B270, 115226. https://doi.org/10.1016/j.mseb.2021.115226
7.        Huang, W., Martin, P., & Zhuang, H. L. (2019). Machine-learning phase prediction of high-entropy alloys. Acta Materialia169, 225-236. https://doi.org/10.1016/j.actamat.2019.03.012
8.        Ji, W., Fu, Z., Wang, W., Wang, H., Zhang, J., Wang, Y., & Zhang, F. (2014). Mechanical alloying synthesis and spark plasma sintering consolidation of CoCrFeNiAl high-entropy alloy. Journal of Alloys and Compounds, 589, 61-66. https://doi.org/10.1016/j.jallcom.2013.11.146
9.        Kang, B., Lee, J., Ryu, H. J., & Hong, S. H. (2018). Ultra-high strength WNbMoTaV high-entropy alloys with fine grain structure fabricated by powder metallurgical process. Materials Science and Engineering: A712, 616-624. https://doi.org/10.1016/j.msea.2017.12.021
10.     King, D. J. M., Middleburgh, S. C., McGregor, A. G., & Cortie, M. B. (2016). Predicting the formation and stability of single phase high-entropy alloys. Acta Materialia104, 172-179. https://doi.org/10.1016/j.actamat.2015.11.040
11.     Long, M., & Rack, H. J. (1998). Titanium alloys in total joint replacement—a materials science perspective. Biomaterials19(18), 1621-1639. https://doi.org/10.1016/S0142-9612(97)00146-4
12.     Maya, A. A., Grana, D. R., Hazarabedian, A., Kokubu, G. A., Luppo, M. I., & Vigna, G. (2012). Zr–Ti–Nb porous alloys for biomedical application. Materials Science and Engineering: C32(2), 321-329. https://doi.org/10.1016/j.msec.2011.10.035
13.     Miracle, D. B., & Senkov, O. N. (2017). A critical review of high entropy alloys and related concepts. Acta materialia122, 448-511. https://doi.org/10.1016/j.actamat.2016.08.081
14.     Nagase, T., Iijima, Y., Matsugaki, A., Ameyama, K., & Nakano, T. (2020). Design and fabrication of Ti–Zr-Hf-Cr-Mo and Ti–Zr-Hf-Co-Cr-Mo high-entropy alloys as metallic biomaterials. Materials Science and Engineering: C107, 110322. https://doi.org/10.1016/j.msec.2019.110322
 
15.     Shittu, J., Pole, M., Cockerill, I., Sadeghilaridjani, M., Reddy, L. V. K., Manivasagam, G., ... & Mukherjee, S. (2020). Biocompatible high entropy alloys with excellent degradation resistance in a simulated physiological environment. ACS Applied Bio Materials3(12), 8890-8900. https://doi.org/10.1021/acsabm.0c01181
16.     Todai, M., Nagase, T., Hori, T., Matsugaki, A., Sekita, A., & Nakano, T. (2017). Novel TiNbTaZrMo high-entropy alloys for metallic biomaterials. Scripta Materialia129, 65-68. https://doi.org/10.1016/j.scriptamat.2016.10.028
17.     Torralba, J. M., Alvaredo, P., & García-Junceda, A. (2019). High-entropy alloys fabricated via powder metallurgy. A critical review. Powder Metallurgy62(2), 84-114. https://doi.org/10.1080/00325899.2019.1584454
18.     Vaidya, M., Muralikrishna, G. M., & Murty, B. S. (2019). High-entropy alloys by mechanical alloying: A review. Journal of Materials Research34(5), 664-686.  https://doi.org/10.1557/jmr.2019.37
19.     Wang, S. P., & Xu, J. (2017). TiZrNbTaMo high-entropy alloy designed for orthopedic implants: As-cast microstructure and mechanical properties. Materials Science and Engineering: C73, 80-89. https://doi.org/10.1016/j.msec.2016.12.057
20.     Wu, Y., Liaw, P. K., & Zhang, Y. (2021). Preparation of bulk TiZrNbMoV and NbTiAlTaV high-entropy alloys by powder sintering. Metals11(11), 1748. https://doi.org/10.3390/met11111748
21.     Yousefi, M., Bahrololoumi Mofrad, N. S., Amiri Kerahroodi, M. S., Barikbin, H. S., & Moudi, M. (2019). Effect of the supplementary aging process on the microstructure and mechanical properties of Mg–5Sn and Mg–5Sn–0.5 Zn Alloys. Transactions of the Indian Institute of Metals72(2), 383-399. https://doi.org/10.1007/s12666-018-1489-3
22.     Yousefi, M., Rahmani, K., Rajabi, M., Reyhani, A., & Asgari, N. (2025). The ensemble learning algorithms for prediction high entropy alloys phases. Afrika Matematika36(3), 117. https://doi.org/10.1007/s13370-025-01334-5
23.     Yousefi, M., Rahmani, K., Rajabi, M., Reyhani, A., & Moudi, M. (2024a). Random forest classifier for high entropy alloys phase diagnosis. Afrika Matematika35(3), 57. https://doi.org/10.1007/s13370-024-01198-1
24.     Yousefi, M., Rajabi, M., Reyhani, A., & Asgari, N. (2024b). Corrosion and biocompatibility properties of TiZrNbCrV, TiZrNbFeCr, and TiZrNbFeV high entropy alloys produced through mechanical alloying. Journal of Materials Engineering and Performance33(24), 14390-14402. https://doi.org/10.1007/s11665-023-08990-3
25.     Yuan, Y., Wu, Y., Yang, Z., Liang, X., Lei, Z., Huang, H., ... & Lu, Z. (2019). Formation, structure and properties of biocompatible TiZrHfNbTa high-entropy alloys. Materials Research Letters7(6), 225-231. https://doi.org/10.1080/21663831.2019.1584592
26.     Zamani, K., Tavoosi, M., & Ghasemi, A. (2023). Structural and Phase Stability in the 2TiC-Al-Ti System During Milling and Subsequent Annealing. https://doi.org/10.30501/acp.2024.431563.1142
27.     Zýka, J., Málek, J., Pala, Z., Andršová, I., & Veselý, J. (2015). Structure and mechanical properties of TaNbHfZrTi high entropy alloy. In Metal 2015—24th International Conference on Metallurgy and Materials (p. 1687). Ostrava, Czech Republic: Tanger. https://konsys.tanger.cz/files/proceedings/21/papers/3963.pdf
دوره 14، شماره 4
زمستان 1404

  • تاریخ دریافت 13 آذر 1404
  • تاریخ بازنگری 02 دی 1404
  • تاریخ پذیرش 14 دی 1404