مواد و فناوری‌های پیشرفته

مواد و فناوری‌های پیشرفته

مطالعه رفتار خوردگی پوشش‌های نانو و آمورف ایجادشده بر روی آلیاژ مونل 400 مورداستفاده در صنایع دریایی

نوع مقاله : مقاله کامل پژوهشی

نویسندگان
فرزاد حبیبی
پروانه فرشباف
دکتری تخصصی، دانشکده ی مهندسی مواد، دانشگاه صنعتی تبریز (سهند)، تبریز، آذربایجان شرقی، ایران
10.30501/jamt.2025.544792.1338
چکیده
در این پژوهش به بررسی و مقایسه رفتار خوردگی پوشش‌های نانوساختار فولاد تندبر کبالتی (HSS M35) و آمورف تیتانیوم، ایجاد‌شده به‌روش لایه‌نشانی جرقه‌زنی الکتریکی (ESD) بر روی زیرلایه آلیاژ مونل 400 پرداخته شده است. پوشش‌ها تحت دو سطح انرژی ورودی متفاوت (ظرفیت خازن 100 و 300 میکروفاراد) ایجاد شدند. مطالعات ریزساختاری نشان داد که پوشش فولاد تندبر دارای ریزساختار نانوکریستالی متشکل از فاز آستنیتی (Ni,Fe) و نانوذرات کاربیدی است؛ در‌حالی‌که پوشش تیتانیوم به‌دلیل نرخ سرمایش فوق‌سریع و آلیاژسازی با عناصر زیرلایه (Ni,Cu)، ساختاری آمورف تشکیل داده است. نتایج آزمون پلاریزاسیون پتانسیودینامیک در محلول 5/3% وزنی NaCl حاکی از بهبود چشمگیر مقاومت به خوردگی هر دو پوشش نسبت به زیرلایه خالص مونل 400 بود؛ به‌طوری‌که چگالی جریان خوردگی (icorr) پوشش تیتانیوم آمورف (μA/cm² 006/0) حدود 5/1 برابر کمتر از پوشش نانوکریستالی فولاد تندبر (μA/cm² 009/0) و 70 برابر کمتر از زیرلایه بدون پوشش (μA/cm² 42/0) بود. این برتری عالی پوشش آمورف ناشی از عدم وجود مرز دانه، عیوب بلوری و توانایی تشکیل یک لایه غیر‌فعال یکنواخت و پایدار است. همچنین پوشش نانوکریستالی HSS با ضخامت 95 میکرون، زیرلایه را در برابر نفوذ محیط خورنده محافظت می‌کند و مقاومت به خوردگی آن را بهبود می بخشد. با‌توجه‌به عملکرد برتر پوشش آمورف تیتانیوم در آزمون خوردگی، این پوشش برای کاربردهای دریایی که مقاومت به خوردگی عامل کلیدی است، پیشنهاد می‌شود.
کلیدواژه‌ها
لایه¬
؛ نشانی جرقه¬
؛ زنی الکتریکی، پوشش نانو‌فولاد تندبر، پوشش آمورف تیتانیوم، آلیاژ مونل

موضوعات

عنوان مقاله English

Study of the Corrosion Behavior of Nano and Amorphous Coatings deposited on Monel 400 Alloy Used in Marine Industries

نویسندگان English

Farzad Habibi
Parvaneh Farshbaf
Materials Engineering Faculty, Sahand University of Technology, Tabriz, Iran.
چکیده English

This research investigates and compares the corrosion behavior of nanocrystalline cobalt high-speed steel (HSS M35) and amorphous titanium coatings deposited on a Monel 400 alloy substrate using the Electro-Spark Deposition (ESD) method. The coatings were produced under two different input energy levels (capacitances of 100 and 300 μF). Microstructural analysis revealed that the high-speed steel coating possessed a nanocrystalline structure comprising an austenitic (Ni, 3Fe) phase and carbide nanoparticles, whereas the titanium coating, owing to ultra-rapid cooling and alloying with substrate elements (Ni, Cu), formed an amorphous structure. Potentiodynamic polarization tests in 3.5 wt.% NaCl solution indicated a significant enhancement in corrosion resistance for both coatings compared to the bare Monel 400 substrate. The corrosion current density (icorr) of the amorphous titanium coating (0.006 μA/cm²) was approximately 1.5 times lower than that of the nanocrystalline high-speed steel coating (0.009 μA/cm²) and about 70 times lower than the uncoated substrate (0.42 μA/cm²). The superior performance of the amorphous coating is attributed to the absence of grain boundaries and crystalline defects, as well as its ability to form a uniform and stable passive layer. Additionally, the nanostructured HSS coating, with a thickness of 95 µm, effectively protects the substrate from the aggressive medium, thereby improving corrosion resistance. Considering the superior performance of the amorphous titanium coating in corrosion tests, it is recommended for marine applications where corrosion resistance is a critical requirement.

کلیدواژه‌ها English

High Speed Steel
Amorphous Titanium
Monel 400
ElectroSpark Deposition
 
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مواد و فناوری‌های پیشرفته
دوره 14، شماره 3
پاییز 1404
صفحه 11-26

  • تاریخ دریافت 22 شهریور 1404
  • تاریخ بازنگری 04 مهر 1404
  • تاریخ پذیرش 22 آبان 1404