نوع مقاله : مقاله کامل پژوهشی
نویسندگان
1 کارشناسی ارشد، دانشکده مهندسی معدن و متالورژی، دانشگاه یزد، یزد، یزد، ایران
2 دانشیار، دانشکده مهندسی معدن و متالورژی، دانشگاه یزد، یزد، یزد، ایران
چکیده
در طی سالهای اخیر، توجه بسیاری از پژوهشگران به نانوذرات فریت کبالت بهمنزله یک ماده مغناطیسی پرکاربرد در ساخت تجهیزات الکترونیکی، مغناطیسی و پزشکی جلب شده است. بر این اساس، در پژوهش حاضر نیز، فرایند تولید این نانوذرات با استفاده از روش سل - ژل در حضور عسل بررسی شد. به این منظور، نمونههایی در حضور 0، 5/0، 1، 5/1، 2 و 5/2 گرم عسل تولید شدند. بهمنظور ارزیابی خواص ساختاری، ریزساختاری و مغناطیسی نانوذرات تولیدشده، آزمونهای پراش پرتو ایکس (XRD)، آنالیز حرارتی افتراقی (DTA) و وزنسنجی حرارتی (TG)، میکروسکوپ الکترونی روبشی نشر میدانی (FESEM) و آزمون مغناطش سنج نمونه نوسانی (VSM) بر روی نمونهها انجام شد. بررسیهای فازشناسی نشان داد که یک ساختار بلوری و تکفاز از فریت کبالت در حضور عسل تشکیل میشود. همچنین، نتایج آزمون FTIR نشان داد که در حضور عسل به میزان چشمگیری از شدت باندهای آلی کاسته میشود. از سوی دیگر، حضور این عامل بهواسطه افزایش پایداری ژل و همچنین افزایش حرارت تولیدی در مرحله پخت سبب ایجاد تغییرات شدیدی در اندازه، شکل ظاهری و همچنین خواص مغناطیسی نانوذرات تولیدی شد. افزودن عسل، با کاهش اندازه ذرات نانوبلورکها و نانوذرات تولیدشده، افزایش نیروی وادارندگی مغناطیسی را به همراه داشت، بهگونهای که در نمونه حاوی 5/1 گرم عسل، این پارامتر مغناطیسی تا حدود 1580 اورستد افزایش یافت. همچنین، مغناطش اشباع نیز در حضور عسل بیشتر از نمونه خام بود.
کلیدواژهها
موضوعات
عنوان مقاله [English]
The Effect of Honey Addition on the Properties of CoFe2O4 Nanoparticles Synthesized by the Sol-Gel Auto-Combustion Method
نویسندگان [English]
- Bahareh Fallah 1
- Saeed Hasani 2
- Alireza Mashreghi 2
1 M. Sc., Department of Mining and Metallurgical Engineering, Yazd University, Yazd, Yazd, Iran
2 Associate Professor, Department of Mining and Metallurgical Engineering, Yazd University, Yazd, Yazd, Iran
چکیده [English]
In recent years, cobalt ferrite nanoparticles have attracted the attention of many researchers due to their vast industrial applications. In this regard, the current study aimed to synthesize CoFe2O4 nanoparticles in the presence of different amounts of honey (0, 0.5, 1, 1.5, 2, and 2.5 g) through the sol-gel auto-combustion method. In order to investigate the microstructure as well as the structural and magnetic properties of the synthesized samples, XRD, DTA/TG, FTIR, FESEM, and VSM analyses were carried out. The phase analysis confirmed that the high-purity cobalt ferrite nanoparticles were formed after the calcination process. The FTIR results showed that the intensity of the organic bands was significantly reduced by adding honey. However, the presence of this agent caused severe changes in the morphology of nanoparticles and also their magnetic properties. Reducing the particle and average grain sizes of the nanoparticles by the addition of honey caused an increase in their coercivity and consequently, their magnetic parameters were enhanced to about 1580 Oe in the sample containing 1.5 g of honey. In addition, the saturation magnetization increased in the presence of honey, compared to the raw sample.
کلیدواژهها [English]
- Cobalt Ferrite
- Sol-Gel
- Coercivity
- Saturation Magnetization
- Honey
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