Document Type : Original Reaearch Article
Authors
1 Material and Energy research Center, Department of Nanotechnology and Advanced Material, Karaj, Iran
2 Material and Energy research Center, Department of Nanotechnology and Advanced Material, Karaj, Iran.
Abstract
In the present work, charged graphene oxide (GO) layers were synthesized using conventional modified Hummer’s method. A thin film of GO was deposited using electrophoretic deposition technique from stable aqueous colloidal suspension of GO layers on hydrophobic surface of crystalline silicon (c-Si) samples. Surface modification with Ag particles was performed in order to improve surface adhesion of graphene oxide layers on hydrophobic silicon surface. Reduction process of deposited GO layer was performed at a temperature of 400 ºC under argon gas flow. The x-ray diffraction pattern showed that graphite layers with oxygen functional groups and increased interlayer spacing were successfully obtained using improved Hummer’s technique. Scanning electron microscopy micrographs showed that non-uniform GO layers were formed on silicon hydrophobic surface. Enhanced surface adhesion and deposition of a uniform thin film of GO was achieved via surface modification using Ag particles. Raman spectra of deposited films proved the existence of GO layers which were reduced.
Keywords
- Soref, R., Applications of silicon-based optoelectronics, MRS Bulletin, 1998, 23, (04), pp. 20-24.
- Chen, L., He, H., Yu, H., Cao, Y., and Yang, D., Fabrication and photovoltaic conversion enhancement of graphene/n-Si Schottky barrier solar cells by electrophoretic deposition, Electrochimica Acta, 2014, 130, 279-285.
- Miao, X., Tongay, S., Petterson, M.K., Berke, K., Rinzler, A.G., Appleton, B.R., and Hebard, A.F., High efficiency graphene solar cells by chemical doping, Nano letters, 2012, 12 , (6), 2745-2750.
- Zhu, Y., Sun, Z., Yan, Z., Jin, Z., and Tour, J.M., Rational design of hybrid graphene films for high-performance transparent electrodes, ACS nano, 2011, 5, (8), 6472-6479.
- Kim, J., Joo, S.S., Lee, K.W., Kim, J.H., Shin, D., Kim, S., and Choi, S.-H., Near-ultraviolet-sensitive graphene/porous silicon photodetectors, ACS applied materials & interfaces, 2014, 6, (23), 20880-20886.
- Regan, W., Alem, N., Alemán, B., Geng, B., Girit, C., Maserati, L., Wang, F., Crommie, M., and Zettl, A., A direct transfer of layer-area graphene, Applied Physics Letters, 2010, 96, (11), 113102.
- An, S.J., Zhu, Y., Lee, S.H., Stoller, M.D., Emilsson, T., Park, S., Velamakanni, A., An, J., and Ruoff, R.S., Thin film fabrication and simultaneous anodic reduction of deposited graphene oxide platelets by electrophoretic deposition, The Journal of Physical Chemistry Letters, 2010, 1, (8), 1259-1263.
- Marcano, D.C., Kosynkin, D.V., Berlin, J.M., Sinitskii, A., Sun, Z., Slesarev, A., Alemany, L.B., Lu, W., and Tour, J.M.: ‘Improved synthesis of graphene oxide’, ACS nano, 2010, 4, (8), pp. 4806-4814.
- Teradal, N.L., Narayan, P.S., Satpati, A.K., and Seetharamappa, J., Fabrication of electrochemical sensor based on green reduction of graphene oxide for an antimigraine drug, rizatriptan benzoate, Sensors and Actuators B: Chemical, 2014, 196, pp. 596-603.
- Spyrou, K., and Rudolf, P., An introduction to graphene, Functionalization of graphene, 2014, 1-20.
- Zhang, H.-B., Zheng, W.-G., Yan, Q., Yang, Y., Wang, J.-W., Lu, Z.-H., Ji, G.-Y., and Yu, Z.-Z., Electrically conductive polyethylene terephthalate/graphene nanocomposites prepared by melt compounding, Polymer, 2010, 51, (5), pp. 1191-1196.
- Childres, I., Jauregui, L.A., Park, W., Cao, H., and Chen, Y.P., Raman spectroscopy of graphene and related materials, New developments in photon and materials research, 2013, 1.