Document Type : Research Note Article

Authors

Materials & Energy Research Center, Department of Ceramic, Karaj, Iran.

Abstract

The objective of this study is to assess the uptake of Cd2+, from aqueous solution by nano hydroxyapatite granular in fixed bed reactor system was investigated. The study also investigates the effects of parameters such as initial concentration ion, bed depth, and flow rate. The breakthrough time and exhaustion time decreased with increasing initial Cd2+ concentration, decreasing bed depth and increasing flow rate. The Thomas model and Yoon-Nelson model were applied to the experimental results for measurement adsorption capacity. Thomas and Yoon-Nelson model predictions were in good agreement with the experimental data. Adsorption capacity and time required for 50% adsorbate breakthrough obtained for initial concentrations of 300, 400 and 500 mg/L of divalent cadmium ions are 2425.95, 2679.14, 4265.51 mg/g of adsorbent, and 18.33, 15.18 and 19.33 min, respectively.

Keywords

  1.  1. Dwivedi, C. P., Sahu, J. N., Mohanty, C. R., Raj Mohan, B., and Meikap, B. C., 'Column Performance of Granular Activated Carbon Packed Bed for Pb(П) Removal', Journal of Hazardous Materials, 2008, 156, 596-603.
  2. 2.
  3. Baird, C. “Environmental Chemistry” W.H.Freeman and Company, McGraw Hill, New York, (1995).
  4. Smiciklas, I., Dimovic, S. Plecas , I. Mitric, M. " Removal of Co2+ from aqueous solutions by hydroxyapatite", Water Research, 2006, 40, 2267 – 2274.
  5. Gomez del Rıo, J.A., Morandoa, P.J., Cicerone, D.S., " Natural materials for treatment of industrial effluents: comparative study of the retention of Cd, Zn and Co by calcite and hydroxyapatite. Part I: batch experiments", Environ Manage, 2004, 71,169–177.
  6. Chaturvedi, P. K., Shekhar Seth, C., Misra, V.," Sorption kinetics and leachability of heavy metal from the contaminated soil amended with immobilizing agent (humus soil and hydroxyapatite)", Chemosphere, 2006, 64, 1109–1114.
  7. Baillez, S., Nzihou, A. Bernache-Assolant, D., Champion, E., Sharrock, P., " Removal of aqueous lead ions by hydroxyapatites: Equilibria and kinetic processes", Hazard Mater, 2007, A139, 443–446.
  8. Chen, N., Zhang, Z., Feng, C., Li, M., Chen, R., Sugiura, N., Investigations on the batch and fixed-bed column performance of fluoride adsorption by Kanuma mud, Desalination, 2011, 268, p.76-82.
  9. Aksu, Z., Çağatay, S.S., and Gönen, F., 'Continuous Fixed Bed Biosorption of Reactive Dyes by Dried Rhizopus Arrhizus: Determination of Column Capacity', Journal of Hazardous Materials, 2007, 143, 362-71.
  10. Chen, S., Yue, Q., Gao, B., Li, Q., Xu, X., and Fu, K., 'Adsorption of Hexavalent Chromium from Aqueous Solution by Modified Corn Stalk: A Fixed-Bed Column Study', Bioresource Technology, 2012, 113, p.114-20.