Journal of Advanced Materials and Technologies

Journal of Advanced Materials and Technologies

Effect of suspension pH and nozzle diameter on the morphology and flowability of alumina - zircon granules fabricated by a spray dryer

Document Type : Original Reaearch Article

Authors
1 Ph.D. Candidate, Materials Engineering Group, Department of Mining and Metallurgical Engineering, Yazd University, Yazd, Iran.
2 Assistant Professor, Materials Engineering Group, Department of Mining and Metallurgical Engineering, Yazd University, Yazd, Iran.
Abstract
In this study, alumina-zircon granules were prepared under various conditions using a spray dryer. The primary challenge of this research was phase separation resulting from the density difference between alumina and zircon. Therefore, identifying optimal spray-drying conditions to obtain granules without zircon segregation was the main objective. Alumina suspensions containing 15 wt.% zircon and 2 wt.% dispersant were prepared at pH values of 4, 9.5, and 11, and granules were produced using a spray dryer equipped with a 700 μm nozzle. In another part of the study, the effect of spray dryer nozzle size on the morphology and flowability of the granules was investigated. The granules obtained from the alumina-zircon suspension containing 2 wt.% dispersant at pH 9 and prepared using a spray dryer equipped with a 1.5 mm nozzle exhibited excellent flow properties, including a repose angle of 28°, apparent density of 1.02 g/cm³, tapped density of 1.13 g/cm³, Hausner ratio of 1.11, and Carr’s index of 9.9, making them suitable for pressing.
Keywords
Subjects

1.      Chen, J., Yang, H., Xu, C. M., Cheng, J. G., & Lu, Y. W. (2021). Preparation of ZrO2 microspheres by spray granulation. Powder Technology, 385, 234-241. https://doi.org/10.1016/j.powtec.2021.02.067
2.      Durmus, C., & Ozgen, O. S. (2015). Experimental synthesis of granulated zirconia powders by spray dryer. Materials letters, 145, 243-246. https://doi.org/10.1016/j.matlet.2015.01.121
3.      Ewsuk, K. (2001). Powder granulation and compaction. Encyclopedia of Materials: Science and Technology, 7788-7800. https://doi.org/10.1016/B978-0-12-803581-8.12103-4
4.      Garrido, L. B., & Califano, A. N. (2007). Effect of an excess of polyelectrolyte on viscoelastic properties of suspensions of alumina and zircon mixtures. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 302(1-3), 24-30. https://doi.org/10.1016/j.colsurfa.2007.01.036
5.      Höhne, P., Mieller, B., & Rabe, T. (2020). Advancing spray granulation by ultrasound atomization. International Journal of Applied Ceramic Technology, 17(5), 2212-2219. https://doi.org/10.1111/ijac.13534
6.      Khor, K., & Li, Y. (2001). Crystallization behaviors in the plasma-spheroidized alumina/zircon mixtures. Materials letters, 48(2), 57-63. https://doi.org/10.1016/S0167-577X(00)00280-9
7.      Majidian, H., Nikzad, L., Farvizi, M., Razavi, M., & Behzadi, B. (2025). Reactive spark plasma sintering of alumina-mullite-zirconia composites. Ceramics International. https://doi.org/10.1016/j.ceramint.2025.06.101
8.      Mazzei, A., Rodrigues, J., & Pandolfelli, V. (2000). Alumina-mullite-zirconia composites obtained by reaction sintering Part II. R-Curve behavior. Journal of Materials Science, 35, 2815-2824. https://doi.org/10.1023/A:1004743001686
9.      Naglieri, V., Gutknecht, D., Garnier, V., Palmero, P., Chevalier, J., & Montanaro, L. (2013). Optimized slurries for spray drying: Different approaches to obtain homogeneous and deformable alumina-zirconia granules. Materials, 6(11), 5382-5397. https://doi.org/10.3390/ma6115382
10.    Nasrollahnejad, R., Majidian, H., Abadzadeh, T. and Nikzad, L. (2016). Type and amount of the final phases  of alumina-zircon. 5(1), 25-32. (In Persion) https://doi.org/10.30501/jamt.2637.70321
11.    Nouri, S., Hoseinian, F. S., Rezai, B., & Saberyan, K. (2019). New pretreatment method for high-tension electrical separation of zircon from quartz. Transactions of Nonferrous Metals Society of China, 29(8), 1737-1743. https://doi.org/10.1016/S1003-6326(19)65081-8
12.    Pan, Z., Wang, Y., & Sun, X. (2011). Fabrication and characterization of spray dried Al2O3–ZrO2–Y2O3 powders treated by calcining and plasma. Powder technology, 212(2), 316-326. https://doi.org/10.1016/j.powtec.2011.06.004
13.    Sathish, S., Geetha, M., Udayakumar, A., Senthil Kumar, S., & Asokamani, R. (2012). Granulation of nano alumina powder for improved flowability by spray drying. Transactions of the Indian Institute of Metals, 65, 485-490. https://doi.org/10.1007/s12666-012-0158-1
14.    Sharifi, L., & Kalantar, M. (2026). Fabrication and characterization of biphasic Al2O3-ZrSiO4 granules and related composites: Effect of dispersant content. Ceramics International. https://doi.org/10.1016/j.ceramint.2026.01.015
15.    Sharma, S., Sharma, T., Deep, M., & Sharma, A. (2021). Techniques to Determine Powder Flow Properties. International Journal of Contemporary Technology and Research, 3(2), 199-204. https://doi.org/10.46860/cgcijctr.2021.06.31.199
16.    Tsubaki, J., Yamakawa, H., Mori, T., & Mori, H. (2002). Optimization of granules and slurries for press forming. Journal of the Ceramic Society of Japan, 110(1286), 894-898. https://doi.org/10.2109/jcersj.110.894
17.    Yıldız, Ö., & Soydan, A. M. (2019). Synthesis of zirconia toughened alumina nanopowders as soft spherical granules by combining co-precipitation with spray drying. Ceramics International, 45(14), 17521-17528. https://doi.org/10.1016/j.ceramint.2019.05.314
18.    Yu, X., He, C., Liu, M., Liu, X., Guo, Z., Yang, M., …, & Min, X. (2025). Influence of γ-Al2O3 and Al (OH) 3 on the mechanical properties of corundum-zirconia-mullite composite materials prepared using zircon. Ceramics International, 51(17), 23671-23679. https://doi.org/10.1016/j.ceramint.2025.03.054v
Volume 15, Issue 2
Summer 2026
Pages 31-45

  • Receive Date 20 May 2026
  • Revise Date 25 June 2026
  • Accept Date 16 August 2026