Journal of Advanced Materials and Technologies

Journal of Advanced Materials and Technologies

Review of the Effect of Presence of Yttria and Benzotriazole Inhibitor Factor on Electrochemical Properties and Activation of Self-Healing Mechanism in Alumina-Based Coatings

Document Type : Original Reaearch Article

Authors
Saeid Mersagh Dezfuli 1
Masoud Sabzi 2
1 Metallurgy Engineering, Metallic Materials Research Center, Malek Ashtar University of Technology (MUT), Tehran, Iran
2 Young Researchers and Elite Club, Dezful Branch, Islamic Azad University, Dezful, Iran
10.30501/jamt.2019.84402
Abstract
In this study, the effect of yttria and benzotriazole doping on corrosion behavior and activation of self-healing mechanism in Alumina-based nanostructured coatings was investigated. Single-component Alumina, double-component Alumina-Ytteria, and triple-component Alumina-Ytteria-benzotriazole ceramic-based coatings have been ‎layer-deposited over St52 steel surface by the sol-gel process in order to improve the abrasion and corrosion behaviour of this steel. Afterwards, phase analysis, morphology, and topography of these coatings have ‎been carried ‎out respectively by Grazing Incidence X-ray Diffraction (GIXRD), Field Emission Scanning ‎‎Electron Microscopy (FE-SEM), and Atomic Force Microscopy (AFM).‎ Moreover, in order to investigate ‎elemental distribution in layer-deposited coatings, Energy ‎Dispersive Spectroscopy (EDS) ‎was performed.‎ Also, the corrosion behaviour of under-investigation coatings ‎and substrate were studied using electrochemical impedance spectroscopy and potentiodynamic ‎polarization for 1, 48, and 96 hours of immersion in 3.5wt%NaCl solution. GIXRD results revealed the ‎amorphous nature of the coatings and the absence of formation of ‎crystalline structure. AFM and FE-SEM ‎observations revealed intactness of double-component Alumina-Ytteria and Alumina-Ytteria-benzotriazole ‎coatings in comparison with single component Aluminacoating.
Keywords
Alumina-based coatings
Yttria
Benzotriazole
Corrosion behavior
Self-healing mechanism
Sol-gel
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  • Receive Date 09 June 2018
  • Revise Date 16 September 2018
  • Accept Date 30 September 2018